Rotational Spectroscopy Of Chemical Reactions In A Cryogenic Buffer Gas Cell

Carroll, Brandon

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https://hdl.handle.net/2142/116907 Copy

Description

Title

Rotational Spectroscopy Of Chemical Reactions In A Cryogenic Buffer Gas Cell

Author(s)

Carroll, Brandon

Contributor(s)

• McCarthy, Michael C.
• Changala, Bryan

Issue Date

2022-06-24

Keyword(s)

Mini-symposium: Spectroscopy meets Chemical Dynamics

Abstract

Low temperature reactions play a critical role in the chemistry of the interstellar medium (ISM). Measuring the kinetics of these reactions is key to constraining models of ISM chemistry, and to understanding ISM chemistry at large. However, measuring chemical kinetics at temperatures relevant to the ISM presents numerous experimental challenges, including creating homogeneous and cooled reactants. Buffer gas cooling offers a near universal method of achieving uniform electronic, vibrational, rotational, and translational cooling, while consuming minimal sample. When combined with microwave spectroscopy, buffer gas cooling cells offer a unique method for probing reactions occurring at very low temperatures. We will report our progress in building and characterizing a buffer gas cell configuration capable of measuring bimolecular reactions of thermalized species occurring within the cell, and discuss its applications for studying ISM chemistry.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

eng

Handle URL

https://hdl.handle.net/2142/116907&&

DOI

https://doi.org/10.15278/isms.2022.FA05

Copyright and License Information

Copyright 2022 held by the authors

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