University of Illinois Urbana-Champaign

Gas-phase Charge Transfer Electronic Spectroscopy Of Ag+-benzene Complex

Orr, Dylan S.

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WG06_1.pptx
6411.pdf

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https://hdl.handle.net/2142/116850

Description

Title
Gas-phase Charge Transfer Electronic Spectroscopy Of Ag+-benzene Complex
Author(s)
Orr, Dylan S.
Contributor(s)
  • Duncan, Michael A.
  • Colley, Jason E.
Issue Date
2022-06-22
Keyword(s)
Ions
Abstract
Charge transfer electronic spectroscopic results were reported for the Ag+-benzene complex in the gas phase using photodissociation. The Ag+-benzene complex was generated by laser vaporization of a silver rod in combination with pulsing an inert gas seeded with benzene then mass selected and probed using a time-of-flight mass spectrometer. The mass-selected ions were then fragmented and scanned using a solid state OPO capable of scanning through the UV-Visible range. A high-resolution electronic spectrum of Ag+-benzene was reported in the UV-Visible range to determine the upper threshold for the dissociation energy of the Ag+-benzene complex which were compared with previous velocity map imaging results. An unexpected feature was observed in the lower UV region which was attributed to the HOMO-LUMO absorption on an excited benzene ligand.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
eng
Handle URL
https://hdl.handle.net/2142/116850
DOI
https://doi.org/10.15278/isms.2022.WG06
Copyright and License Information
Copyright 2022 held by the authors

Owning Collections

Abstracts & Presentations - 2022 International Symposium on Molecular Spectroscopy PRIMARY