The Soleil View On Prototypical Organic Nitriles: The 13c Species Of Ethyl Cyanide

Endres, Christian

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https://hdl.handle.net/2142/116590 Copy

Description

Title

The Soleil View On Prototypical Organic Nitriles: The 13c Species Of Ethyl Cyanide

Author(s)

Endres, Christian

Contributor(s)

• Thorwirth, Sven
• Schlemmer, Stephan
• Caselli, Paola
• McCarthy, Michael C.
• Bonah, Luis
• Zingsheim, Oliver
• Guillemin, J.-C.
• Pirali, Olivier
• Martin-Drumel, Marie-Aline

Issue Date

2022-06-24

Keyword(s)

Astronomy

Abstract

Vibrational spectra of the three singly substituted $^{13}$C isotopic species of ethyl cyanide, aka propionitrile (CH$_3$CH$_2$CN), have been studied at high spectral resolution at the synchrotron facility SOLEIL using Fourier-transform far-infrared spectroscopy. % up to 700\,cm$^{-1}$. % The measurements, recorded up to 700\,cm$^{-1}$, cover the fundamental modes of the CCN in-plane bending $\nu_{13}$, the methyl torsion $\nu_{21}$, the CCN out-of-plane bending $\nu_{20}$ as well as the CCC in-plane bending $\nu_{12}$. % A first spectroscopic analysis has been performed using the \textit{Automated Spectral Assignment Procedure} (ASAP)\footnote{M. A. Martin-Drumel, C. P. Endres, O. Zingsheim, T. Salomon, J. van Wijngaarden, O. Pirali, S. Gruet, F. Lewen, S. Schlemmer, M. C. McCarthy, and S. Thorwirth 2015, J. Mol. Spectrosc. 315, 72} to derive accurate excited-state rotational level energies with a focus on the $\nu_{20}$ and the $\nu_{12}$ vibrational modes.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

eng

Handle URL

https://hdl.handle.net/2142/116590

DOI

https://doi.org/10.15278/isms.2022.FG07

Copyright and License Information

Copyright 2022 held by the authors

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