University of Illinois Urbana-Champaign

The Soleil View On Prototypical Organic Nitriles: The 13c Species Of Ethyl Cyanide

Endres, Christian

Content Files
FG07_1.pdf
6095.pdf

Permalink

https://hdl.handle.net/2142/116590

Description

Title
The Soleil View On Prototypical Organic Nitriles: The 13c Species Of Ethyl Cyanide
Author(s)
Endres, Christian
Contributor(s)
  • Thorwirth, Sven
  • Schlemmer, Stephan
  • Caselli, Paola
  • McCarthy, Michael C.
  • Bonah, Luis
  • Zingsheim, Oliver
  • Guillemin, J.-C.
  • Pirali, Olivier
  • Martin-Drumel, Marie-Aline
Issue Date
2022-06-24
Keyword(s)
Astronomy
Abstract
Vibrational spectra of the three singly substituted $^{13}$C isotopic species of ethyl cyanide, aka propionitrile (CH$_3$CH$_2$CN), have been studied at high spectral resolution at the synchrotron facility SOLEIL using Fourier-transform far-infrared spectroscopy. % up to 700\,cm$^{-1}$. % The measurements, recorded up to 700\,cm$^{-1}$, cover the fundamental modes of the CCN in-plane bending $\nu_{13}$, the methyl torsion $\nu_{21}$, the CCN out-of-plane bending $\nu_{20}$ as well as the CCC in-plane bending $\nu_{12}$. % A first spectroscopic analysis has been performed using the \textit{Automated Spectral Assignment Procedure} (ASAP)\footnote{M. A. Martin-Drumel, C. P. Endres, O. Zingsheim, T. Salomon, J. van Wijngaarden, O. Pirali, S. Gruet, F. Lewen, S. Schlemmer, M. C. McCarthy, and S. Thorwirth 2015, J. Mol. Spectrosc. 315, 72} to derive accurate excited-state rotational level energies with a focus on the $\nu_{20}$ and the $\nu_{12}$ vibrational modes.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
eng
Handle URL
https://hdl.handle.net/2142/116590
DOI
https://doi.org/10.15278/isms.2022.FG07
Copyright and License Information
Copyright 2022 held by the authors

Owning Collections

Abstracts & Presentations - 2022 International Symposium on Molecular Spectroscopy PRIMARY