Assessing The Performance Of Rotational Spectroscopy In Chiral Analysis

Schnell, Melanie

Permalink

https://hdl.handle.net/2142/111422 Copy

Description

Title

Assessing The Performance Of Rotational Spectroscopy In Chiral Analysis

Author(s)

Schnell, Melanie

Contributor(s)

• Leung, Helen O.
• Marshall, Mark D.
• Perez, Cristobal
• Domingos, Sergio R.

Issue Date

2021-06-25

Keyword(s)

Chirality and stereochemistry

Abstract

The application of rotational spectroscopy-based methods as tools to deliver accurate and precise chirality-sensitive information are still breaking ground, but their applicability in the challenging field of analytical chemistry is already clear. In a recent study, we explored the current capabilities and challenges of microwave 3-wave mixing (M3WM) and chiral tag rotational spectroscopy - two emerging techniques for chiral analysis based on rotational spectroscopy. In this presentation, we compare the performance of these two techniques with respect to solving the absolute configuration and the enantiomeric excess (ee) of a sample prepared by others and containing a mixture of enantiomers of styrene oxide with a composition unknown to us.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

Text

Language

eng

Permalink

http://hdl.handle.net/2142/111422

DOI

10.15278/isms.2021.FM01

Owning Collections