In Search Of Vibrationally Excited State Monodromy In Ncncs

Tokaryk, Dennis W.

Permalink

https://hdl.handle.net/2142/111540 Copy

Description

Title

In Search Of Vibrationally Excited State Monodromy In Ncncs

Author(s)

Tokaryk, Dennis W.

Contributor(s)

• Billinghurst, Brant E.
• De Lucia, Frank C.
• Winnewisser, Brenda P.
• Winnewisser, Manfred
• Ross, Stephen Cary

Issue Date

2021-06-24

Keyword(s)

Mini-symposium: Large Amplitude Motions

Abstract

At previous ISMS meetings we have reported on the effects of monodromy on the $\nu_7$ bending mode of NCNCS. The presence of monodromy was established directly from experimental data collected at the Canadian Light Source. To aid that work we assigned some of the spectrum of the $\nu_7$ manifold built on the $\nu_3$ stretching mode. In this talk we will discuss a more complete assignment of the $\nu_3$+$\nu_7$ spectrum. One of our goals is to consider the impact of stretching on the monodromy of the $\nu_7$ mode. We will attempt to use the same Generalized SemiRigid Bender model as was applied to the pure $\nu_7$ mode.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

Text

Language

eng

Permalink

http://hdl.handle.net/2142/111540

DOI

10.15278/isms.2021.RH11

Owning Collections