A study of the conformational isomerism of n-propyl nitrate by microwave spectroscopy

Stephens, Susanna L.

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https://hdl.handle.net/2142/104430 Copy

Description

Title

A study of the conformational isomerism of n-propyl nitrate by microwave spectroscopy

Author(s)

Stephens, Susanna L.

Contributor(s)

• Blake, Thomas A.
• Brauer, Carolyn
• Cooke, S.A.
• Novick, Stewart E.
• Orellana, W.

Issue Date

2019-06-18

Keyword(s)

Conformers and isomers

Date of Ingest

• 2020-01-25T19:31:49Z
• 2019-07-15T22:16:54Z

Abstract

The rotational spectrum of n-propyl nitrate was measured in the frequency range between 6-18 GHz using a Balle-Flygare Fourier transform microwave jet/cavity spectrometer. Parent, $^{13}$C and $^{15}$N isotopologue transitions for the lower-energy anti-gauche (AG) conformer were found using this instrument. The search for spectra from other conformers was performed using a broadband chirped-pulse jet spectrometer. Transitions from the anti-anti (AA) conformer were observed in this manner. Parent, $^{13}$C and $^{15}$N isotopologue transitions for the AA conformer were rescanned using the cavity instrument to improve resolution and the signal-to-noise ratio. Rotational, centrifugal distortion, and nuclear electric quadrupole coupling constants for all conformers/isotopologues were fit using Pickett’s SPFIT program. The structure of n-propyl nitrate will be discussed in light of these results. \begin{center} \includegraphics[scale=0.6] {PROPYL_NITRATE_1.eps} \end{center}

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Genre of Resource

Conference Paper / Presentation

Language

eng

Permalink

http://hdl.handle.net/2142/104430

DOI

https://doi.org/10.15278/isms.2019.TJ02

Copyright and License Information

Copyright 2019 Susanna L. Stephens

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