University of Illinois Urbana-Champaign

Coordination and structure of late transition metal cation (Co, Rh, Pt) acetylene complexes studied with infrared photodissociation spectroscopy

Marks, Joshua H.

Content Files
1443044.pptx
3932.pdf

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https://hdl.handle.net/2142/104369

Description

Title
Coordination and structure of late transition metal cation (Co, Rh, Pt) acetylene complexes studied with infrared photodissociation spectroscopy
Author(s)
Marks, Joshua H.
Contributor(s)
  • Duncan, Michael A.
  • Ward, Timothy B.
Issue Date
2019-06-18
Keyword(s)
Non-covalent interactions
Date of Ingest
  • 2019-07-15T22:16:47Z
  • 2020-01-25T19:30:22Z
Abstract
Late transition metals are studied as model systems for single atom catalysis in the gas phase with infrared photodissociation spectroscopy. Clusters of M$^{+}$(acetylene)$_{n}$ (n = 1-8) are produced via laser vaporization of either cobalt, rhodium, or platinum rods in a supersonic expansion of argon containing acetylene. Infrared photodissociation spectroscopy of smaller clusters is accomplished with the aid of argon tagging. Larger clusters are studied through the elimination of one or more acetylene ligands. These spectra are assigned with the aid of B3LYP/Def2TZVP computations. The structure and size of the inner coordination sphere is discussed.
Publisher
International Symposium on Molecular Spectroscopy
Type of Resource
text
Genre of Resource
Conference Paper / Presentation
Language
eng
Permalink
http://hdl.handle.net/2142/104369
DOI
https://doi.org/10.15278/isms.2019.TH09
Copyright and License Information
Copyright 2019 Joshua H. Marks

Owning Collections

Abstracts & Presentations - 2019 International Symposium on Molecular Spectroscopy PRIMARY