Soluble redox active macromolecular architectures and their electrochemical analysis for energy storage applications

Montoto Blanco, Elena C

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https://hdl.handle.net/2142/105849 Copy

Description

Title

Soluble redox active macromolecular architectures and their electrochemical analysis for energy storage applications

Author(s)

Montoto Blanco, Elena C

Issue Date

2019-01-08

Director of Research (if dissertation) or Advisor (if thesis)

Rodriguez-Lopez, Joaquin

Doctoral Committee Chair(s)

Rodriguez-Lopez, Joaquin

Committee Member(s)

• van der Veen, Renske
• Moore, Jeffrey S.
• Kenis, Paul J. A.

Department of Study

Chemistry

Discipline

Chemistry

Degree Granting Institution

University of Illinois at Urbana-Champaign

Degree Name

Ph.D.

Degree Level

Dissertation

Keyword(s)

• redox active polymers
• energy storage
• flow batteries
• electrochemical characterization

Abstract

Organic redox-active materials offer advantages of material tunability while maintaining high performance for next-generation energy storage and conversion solutions. Macromolecular architectures such as oligomers, polymers, and colloids have recently gained interest for their size-exclusion capabilities for preventing capacity fades in flow batteries. These architectures are highly tunable and made redox-active by the incorporation of organic redox motifs as pendants. Traditionally, redox active polymers (RAPs) have been electrochemically studied as films or composites, with few examples of solution-based studies until recently. In this dissertation, I explore the design and electrochemical characterization of the redox activity of these RAPs in solution and their behavior at electrode interfaces. The main polymers of interest evaluated contain viologen, ferrocene, and cyclopropenium-based pendant groups. The introduction of crosslinked versions of these polymers, called redox active colloids (RACs), that can be fully excluded from crossing porous membranes are introduced as morphologically controlled redox active material. Importantly, prototype flow battery testing of these RAPs as catholyte/anolyte pairs are investigated for demonstrating their potential use in enabling next-generation nonaqueous redox flow batteries. Alternative applications for these RAPs are also explored by taking advantage of their redox potentials to catalyze chemical reactions in solution. This RAP electrocatalysis is investigated for catalyzing reactions such as peroxide formation in varied lithium environments. For these studies, a combination of experimental techniques including cyclic voltammetry, potential-controlled electrolysis, spectro-electrochemistry, and Galvanostatic cycling were used to characterize RAP and RAC reactivity. In sum, this dissertation elucidates the electrochemical properties of varied macromolecular architectures for use in the field of energy storage.

Graduation Semester

2019-05

Type of Resource

text

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http://hdl.handle.net/2142/105849

Copyright and License Information

Copyright 2019 Elena C. Montoto-Blanco

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