AC Stark effect observed in a microwave-(sub)millimeterwave double resonance experiment
Roenitz, Kevin
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https://hdl.handle.net/2142/100630
Description
Title
AC Stark effect observed in a microwave-(sub)millimeterwave double resonance experiment
Author(s)
Roenitz, Kevin
Contributor(s)
Shipman, Steven
Widicus Weaver, Susanna L.
Smith, Houston H.
McCabe, Morgan N.
Powers, Carson Reed
Hays, Brian M.
Issue Date
2018-06-19
Keyword(s)
Instrument/Technique Demonstration
Abstract
A microwave-(sub)millimeter wave double resonance experiment was developed in order to improve the ease with which one is able to assign spectral lines by displaying the interconnectivity of states. This experiment combines chirped-pulse microwave spectroscopy and fast-sweep (sub)millimeter spectroscopy to increase the speed of data acquisition. During the experiment, the splitting of spectral lines was detected instead of the traditional movement of population seen in other double resonance experiments. The line splitting was determined to be caused by the AC Stark effect. The experimental design along with the resulting double resonance methanol spectra will be presented.
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