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Matrix-isolation FTIR spectroscopy of the 1-butyn-3-yl radical
McCunn, Laura R.
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https://hdl.handle.net/2142/100739
Description
- Title
- Matrix-isolation FTIR spectroscopy of the 1-butyn-3-yl radical
- Author(s)
- McCunn, Laura R.
- Contributor(s)
- Ellis, Martha
- Brown, Glenna J.
- Issue Date
- 2018-06-18
- Keyword(s)
- Radicals
- Date of Ingest
- 2018-08-17T16:09:38Z
- 2018-12-12T22:38:37Z
- Abstract
- The 1-butyn-3-yl radical (C4H5) is thought to play a role in the formation of hydrocarbons in the interstellar medium and planetary atmospheres, but it is not well characterized. In this study, the 1-butyn-3-yl radical was formed by the pyrolysis of gas-phase 3-bromo-1-butyne at temperatures of 800-1200 K. Nascent radicals were isolated in an argon marix, followed by FTIR spectroscopy. Vibrational bands in the experimental spectra were matched to frequencies predicted by Gaussian 09. Pyrolysis of 3-methyl-1-butyne was also investigated as a possible pyrolytic precursor to the 1-butyn-3-yl radical under similar conditions. Evidence of 1-butyn-3-yl formation was observed, but other radicals may have formed as well.
- Publisher
- International Symposium on Molecular Spectroscopy
- Type of Resource
- text
- Genre of Resource
- Conference Paper / Presentation
- Language
- eng
- Permalink
- http://hdl.handle.net/2142/100739
- DOI
- 10.15278/isms.2018.MJ03
- Copyright and License Information
- Copyright 2018 Laura R. McCunn
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