Photoinduced charge transfer in cation-π complexes studied with VMI
Rittgers, Brandon M.
Content Files
1103202.pptx
3006.pdf
Loading…
Download Files
Loading…
Download Counts (All Files)
Loading…
Edit File
Loading…
Permalink
https://hdl.handle.net/2142/100833
Description
Title
Photoinduced charge transfer in cation-π complexes studied with VMI
Author(s)
Rittgers, Brandon M.
Contributor(s)
Duncan, Michael A.
Leicht, Daniel
Issue Date
2018-06-22
Keyword(s)
Ions
Date of Ingest
2018-08-17T16:09:52Z
2018-12-12T22:37:52Z
Abstract
The photodissociation charge transfer processes of Ag+ cation-π complexes with small aromatics were studied using velocity map imaging. Ions formed by laser vaporization are pulse extracted and mass-selected in a linear time-of-flight mass spectrometer. The ion beam is then intersected with a UV laser causing dissociation, and the ions are detected using a fast-phosphor screen. The detector has spatial resolution which allows us to extract the total kinetic energy release of the dissociation process, which gives us information on the binding energy of the ion. Excitation with 355 nm lead to the dissociative charge transfer of Ag+-toluene and Ag+-furan, as seen previously with the Ag+-benzene complex.
Use this login method if you
don't
have an
@illinois.edu
email address.
(Oops, I do have one)
IDEALS migrated to a new platform on June 23, 2022. If you created
your account prior to this date, you will have to reset your password
using the forgot-password link below.
1103202.pptx
3006.pdf
