The conformer specific room-temperature rotational spectrum of allyl chloride utilizing strong field coherence breaking
Riffe, Erika
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https://hdl.handle.net/2142/100712
Description
Title
The conformer specific room-temperature rotational spectrum of allyl chloride utilizing strong field coherence breaking
Author(s)
Riffe, Erika
Contributor(s)
Hernandez-Castillo, Alicia O.
Fritz, Sean
Shipman, Steven
Johnson, Erika
Zwier, Timothy S.
Issue Date
2018-06-19
Keyword(s)
Instrument/Technique Demonstration
Abstract
The 8-26.5 GHz conformer specific rotational spectrum of allyl chloride was recorded in a room temperature spectrometer using the strong field coherence breaking (SFCB) technique.a Allyl chloride, which has cis- and skew- conformers as well as 35Cl and 37Cl isotopologues, was chosen as the initial molecule for testing this method in the room temperature chirped pulse waveguide setup.b This data was compared to results from the SFCB technique performed at Purdue University using a jet expansion at 1-2K. The application of this and other methods for the simplification of room temperature spectra will be discussed.
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