Microwave spectrum of the a internal rotor state of Ar-CH3I
Huff, Anna
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https://hdl.handle.net/2142/100580
Description
Title
Microwave spectrum of the a internal rotor state of Ar-CH3I
Author(s)
Huff, Anna
Contributor(s)
Leopold, Ken
Smith, CJ
Issue Date
2018-06-21
Keyword(s)
Clusters/Complexes
Abstract
The Ar-CH3I complex has been observed by pulsed-nozzle Fourier transform microwave spectroscopy. The rotational spectrum is complicated by both the low internal rotation barrier of the methyl group and the large nuclear quadrupole coupling from the iodine. The identification of closed loops was essential to the successful analysis of 140 observed transitions which have been assigned to the A internal rotor state of the complex. An additional 102 observed transitions are likely due to the E internal rotor state. Associated computational work, as well as ongoing attempts to assign the E state spectrum, will be discussed.
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