The structure of gauche-butadiene: Insights from the centimeter, millimeter, and FIR-infrared high resolution spectra
Martin-Drumel, Marie-Aline
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https://hdl.handle.net/2142/100812
Description
Title
The structure of gauche-butadiene: Insights from the centimeter, millimeter, and FIR-infrared high resolution spectra
Author(s)
Martin-Drumel, Marie-Aline
Contributor(s)
McCarthy, Michael C.
Stanton, John F.
Pirali, Olivier
Ellison, Barney
Porterfield, Jessie P.
Nava, Matthew
Changala, Bryan
Baraban, Joshua H.
Issue Date
2018-06-20
Keyword(s)
Mini-symposium: Far-Infrared Spectroscopy
Abstract
Recent investigation of the centimeter spectrum of gauche-butadiene has unambiguously established a non-planar conformation for this fundamental, archetypal diene for the Diels-Alder reaction [1]. We will present subsequent theoretical and experimental investigations aimed at determining a highly accurate molecular structure and the barrier height for interconversion between the two equivalent tunneling gauche forms.
[1] J. H. Baraban, M.-A. Martin-Drumel, et al., Angewandte Chemie, 57, 1821 (2018)
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