Formamide, water, and their complexes: A microwave spectroscopy study
Blanco, Susana
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https://hdl.handle.net/2142/100673
Description
Title
Formamide, water, and their complexes: A microwave spectroscopy study
Author(s)
Blanco, Susana
Contributor(s)
Pate, Brooks
Holdren, Martin S.
West, Channing
Lopez, Juan Carlos
Issue Date
2018-06-20
Keyword(s)
Clusters/Complexes
Abstract
The rotational spectra of formamide and water mixtures have been recorded in the 2-8 GHz frequency region using a chirped-pulse Fourier transform microwave spectrometer. Samples of 14N and 15N of formamide have been used in this work. The 14N quadrupole coupling hyperfine structure is a tool to identify the structure of the observed complexes; the 15N isotopologue is of great help to explore the conformational panorama of complexes with several formamide units. In this work we present the detection and characterization of complexes of formamide and formamide-water, as F3 and F-(H2O)4, which show interesting structural features.
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