The curious(er) case of mass 63: A thrilling and confusing sequel
Blackstone, Christopher C
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https://hdl.handle.net/2142/100789
Description
Title
The curious(er) case of mass 63: A thrilling and confusing sequel
Author(s)
Blackstone, Christopher C
Contributor(s)
Sanov, Andrei
Issue Date
2018-06-18
Keyword(s)
Structure determination
Abstract
Produced in a reaction or interaction either between methanol and methoxide or methoxide and oxygen, an unexpected and difficult to identify species has appeared in our mass spectrum. We seek to narrow its molecular formula to one of CH3O3 or C2H7O2 using fully deuterated methanol as a precursor to separate the two formulas by mass, and to further use the photoelectron spectrum and a fragmentation spectrum of the fully deuterated species to most accurately determine the molecular identity and completely assign its photoelectron spectrum.
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