Rotational-predissociation double resonance spectroscopy of the He-HCO+ complex
Schlemmer, Stephan
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https://hdl.handle.net/2142/100650
Description
Title
Rotational-predissociation double resonance spectroscopy of the He-HCO+ complex
Author(s)
Schlemmer, Stephan
Contributor(s)
Asvany, Oskar
Surin, Leonid
Kohguchi, Hiroshi
Schreier, Phillip
Töpfer, Matthias
Salomon, Thomas
Issue Date
2018-06-22
Keyword(s)
Fundamental interest
Abstract
Cation-Helium complexes are interesting spectroscopic systems due to the floppy bond of the helium atom. HeHCO+ is a particularly interesting test system, as it is linear and has a 1Σ ground state. So far experimental data have been limited to infrared studies on the ν1 C-H stretching mode of He-HCO+. In order to obtain high-resolution rotational data the recently developed rotational-predissociation double resonance method has been applied to this complex. Accurate molecular parameters will be presented and discussed.
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