High resolution rotational spectroscopy of CH3+-He
Schlemmer, Stephan
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https://hdl.handle.net/2142/100646
Description
Title
High resolution rotational spectroscopy of CH3+-He
Author(s)
Schlemmer, Stephan
Contributor(s)
Asvany, Oskar
Kohguchi, Hiroshi
Yamada, Koichi M.T.
Dopfer, Otto
Salomon, Thomas
Töpfer, Matthias
Issue Date
2018-06-22
Keyword(s)
Comparing theory and experiment
Abstract
Using an infrared and millimeter double resonance action spectroscopic scheme in a cryogenic ion trap, high resolution rotational transitions are recorded for the (near) symmetric top CH+ 3 -He. Eighteen rotational transitions up to J 00 = 6 are recorded in the range 60 - 410 GHz. Small unexpected splittings are resolved for K = 1. Advantages of this novel approach of high-resolution ion spectroscopy and potential future applications to spectra of cold cation-helium complexes are discussed.
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