Microwave and FIR spectroscopy of dimethylsulfide in the ground, first and second excited torsional states

Ilyushin, V.

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https://hdl.handle.net/2142/96881 Copy

Description

Title

Microwave and FIR spectroscopy of dimethylsulfide in the ground, first and second excited torsional states

Author(s)

Ilyushin, V.

Contributor(s)

• Maul, Christof
• Bauerecker, Sigurd
• Manceron, Laurent
• Jabri, Atef
• Kwabia Tchana, F.
• Motiyenko, R.A.
• Margulès, L.
• Alekseev, E.A.
• Krapivin, Igor
• Pogrebnyak, Mykola
• Dorovskaya, Olga
• Armieieva, Iuliia

Issue Date

2017-06-20

Keyword(s)

• Large amplitude motions
• Internal rotation

Abstract

A new study footnote{ This work was done under support of the Volkswagen foundation. The assistance of Science and Technology Center in Ukraine is acknowledged (STCU partner project P686).} of the dimethylsulfide ((CH$_{3}$)$_{2}$S) spectrum is reported. The new measurements have been carried out using the Kharkiv spectrometer in the Institute of Radio Astronomy of NASU (Ukraine) and using the Lille spectrometer in the PhLAM laboratory (France). The new millimeter and submillimeter wave measurements cover the frequency range from 49 GHz to 660 GHz. The rotational transitions belonging to the three lowest torsional states of the molecule as well as the new assignments in the FIR torsional band (AILES beamline of the synchrotron SOLEIL) and the microwave data available in the literature footnote{ A. Jabri, V. Van, H. V. L. Nguyen, H. Mouhib, F. Kwabia Tchana , L. Manceron , W. Stahl, I. Kleiner, A&A 589, A127 (2016).} have been analyzed using recently developed model for the molecules with two equivalent methyl rotors and C$_{2v}$ symmetry at equilibrium (PAM_C2v_2tops program)footnote{ Ilyushin V. V., Hougen J. T. J. Mol. Spectrosc. 289 (2013) 41-49.}. In the talk the details of this new study will be discussed.

Publisher

International Symposium on Molecular Spectroscopy

Type of Resource

text

Language

eng

Permalink

http://hdl.handle.net/2142/96881

DOI

https://doi.org/10.15278/isms.2017.TI03

Copyright and License Information

Copyright 2017 V. Ilyushin

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