Microwave spectrum of 1-sila-1-isocyanocyclopent-3-ene
Grubbs, G.S., II
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https://hdl.handle.net/2142/97071
Description
Title
Microwave spectrum of 1-sila-1-isocyanocyclopent-3-ene
Author(s)
Grubbs, G.S., II
Contributor(s)
Persinger, Thomas D.
Moon, Nicole
Wurrey, Charles J.
Palmer, Michael H.
Guirgis, Gamil A.
Hickman, Daniel V.
Marshall, Frank E.
Issue Date
2017-06-23
Keyword(s)
(Hyper)fine structure
Tunneling
Abstract
The microwave spectrum of synthesized molecule, 1-sila-1-isocyanocyclopent-3-ene has been studied using chirped pulse and cavity Fourier transform microwave (CP-FTMW and FTMW) techniques. The rotational spectrum has been assigned along with hyperfine splitting due to the $^{14}$N nucleus. Very limited sample could be synthesized at a time with this molecule, demonstrating the power of the CP-FTMW technique. Analysis of the molecule, along with structural possibilities will be discussed.
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