Taking the next step with halogenated olefins: Microwave spectroscopy and molecular structures of tetrafluoro- and chloro-trifluoro propenes and their complexes with the argon atom
Marshall, Mark D.
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https://hdl.handle.net/2142/96817
Description
Title
Taking the next step with halogenated olefins: Microwave spectroscopy and molecular structures of tetrafluoro- and chloro-trifluoro propenes and their complexes with the argon atom
Author(s)
Marshall, Mark D.
Contributor(s)
Dao, Alina K.
Randy-Cofie, Allison M.
Hoque, Laboni
Tracy, Megan E.
Wronkovich, Miles A.
Leung, Helen O.
Issue Date
2017-06-20
Keyword(s)
Structure determination
Abstract
The determination of the structures of heterodimers of haloethylenes with protic acids has provided a wealth of information and a few surprises concerning intermolecular forces and the sometimes cooperative and sometimes competing effects of electrostatic, steric, and dispersion forces. In seeking to apply this knowledge to larger systems with a wider variety of possible interactions and binding sites, we extend the carbon chain by one atom via the addition of a trifluoromethyl moeity. As a first step the microwave rotational spectra of the halopropene monomers, 2,3,3,3-tetrafluoropropene, 2-chloro-3,3,3-trifluoropropene, ({it E})-1-chloro-3,3,3-trifluoropropene, and ({it Z})-1-chloro-3,3,3-trifluoropropene, and their complexes with the argon atom are obtained and analyzed to obtain molecular structures.
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