The ν3 fundamental vibrational band of SCCCS revisited
Thorwirth, Sven
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https://hdl.handle.net/2142/96828
Description
Title
The ν3 fundamental vibrational band of SCCCS revisited
Author(s)
Thorwirth, Sven
Contributor(s)
Dudek, John B.
Salomon, Thomas
Issue Date
2017-06-23
Keyword(s)
Clusters/complexes
Abstract
The $nu_3$ fundamental vibrational band of carbon subsulfide, SCCCS, first studied by Holland_x000d_
and collaboratorsfootnote{F. Holland, M. Winnewisser, C. Jarman, H. W. Kroto, and K. M. T. Yamada 1988, textit{J. Mol. Spectrosc.} 130, 344}$^,$footnote{F. Holland and M. Winnewisser 1991, textit{J. Mol. Spectrosc.} 147, 496} has been reinvestigated using a combination of laser ablation production, free-jet expansion and quantum cascade laser spectroscopy. In addition to the fundamental band (located at 2100,cm$^{-1}$) and associated hot bands originating from the lowest bending mode $nu_7$, the hot bands from the two energetically higher-lying bending modes $nu_5$ and $nu_6$ have been observed for the first time as has the S$^{13}$CCCS isotopic species.
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