Chirped-pulse Fourier transform microwave spectroscopy of the 2,3-difluoropyridine-carbon dioxide complex
Brown, Gordon G.
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https://hdl.handle.net/2142/96917
Description
Title
Chirped-pulse Fourier transform microwave spectroscopy of the 2,3-difluoropyridine-carbon dioxide complex
Author(s)
Brown, Gordon G.
Contributor(s)
Funderburk, Cameron M.
Gaster, Sydney A.
Issue Date
2017-06-20
Keyword(s)
Structure determination
Abstract
The pure rotational spectrum of the 2,3-difluoropyridine-CO$_{2}$ complex was measured on a chirped-pulsed Fourier transform microwave (CP-FTMW) spectrometer in the 3 – 18 GHz frequency range. The spectrum was analyzed to find the spectroscopic constants of the complex, including the quadrupole coupling constants and the centrifugal distortion constants. The spectrum of the 2,3-difluoropyridine-$^{13}$CO$_{2}$ complex was also measured and analyzed. Experimental constants were compared to the results of emph{ab initio} calculations.
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