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Optimized Antioxidants for Biodiesel

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Title: Optimized Antioxidants for Biodiesel
Author(s): Larson, Richard A.; Marley, Karen A.
Subject(s): Biodiesel fuels -- Research Oxidation chemistry
Abstract: Methods to improve the oxidative stability of B100 biodiesel were studied. A combination of a peroxide destroyer - triphenylphosphine - and a chain-breaking antioxidant - propyl gallate - was found to largely prevent oxidative damage in soy- and waste oil-derived biodiesels. Peroxides were shown to react rapidly with propyl gallate and render it ineffective. Triphenylphosphine alone provided some protection from oxidation, but not to the extent of the combination. Propyl gallate was found to be superior to other potential surface-active or chain-breaking antioxidants tested, such as ascorbyl palmitate, butylated hydroxytoluene (BHT), Trolox, and other gallate esters.
Issue Date: 2011-09
Publisher: Champaign, IL : Illinois Sustainable Technology Center
Citation Info: Larson, Richard A.; Marley, Karen A. Optimized Antioxidants for Biodiesel. Champaign, IL : Illinois Sustainable Technology Center, 2011.
Series/Report: TR Series (Sustainable Technology Center) ; 046
Genre: Technical Report
Type: Text
Language: English
URI: http://hdl.handle.net/2142/27682
Publication Status: published or submitted for publication
Peer Reviewed: is peer reviewed
Sponsor: Illinois Sustainable Technology Center/ Contract No. HWR09213
Date Available in IDEALS: 2011-09-28
 

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